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脫硫設備的工藝原理及特性
法脫硫工藝的整個過程包括冷卻、吸收、再熱、石膏回收、原料調製等工序。脫硫脫硝設備工藝用霧化的石灰漿液在噴霧幹燥塔中與煙氣接觸,石灰漿液與SO2反應後生成一種幹燥的固體反應物,然後連同飛灰一起被除塵器收集。工業汙水處理目前,國內外常用的煙氣脫硫方法按其工藝大致可分為三類:濕式拋棄工藝、濕式回收工藝和幹式工藝。其中變頻器在設備中的應用為節約能源做出了巨大貢獻。煙氣中的二氧(Oxygen)化硫氣體在玻璃鋼脫硫塔內與碳酸鈣吸收液進行氣液接觸。反應如下:脫硫塔內:CaCO3+SO3+12H2O CaSO3?12H2O+CO2氧化塔內:CaSO3?12H2O+32O2+32H2O CaSO4+2H2O2。
The entire process of desulfurization technology includes cooling, absorption, reheating, gypsum recovery, raw material preparation, and other procedures. The atomized lime slurry used in the desulfurization and denitrification equipment process is in contact with the flue gas in the spray drying tower. The lime slurry reacts with SO2 to generate a dry solid reactant, which is then collected by the dust collector together with the fly ash. At present, the commonly used flue gas desulfurization methods for industrial wastewater treatment at home and abroad can be roughly divided into three categories according to their processes: wet abandonment process, wet recovery process, and dry process. The application of frequency converters in equipment has made significant contributions to energy conservation. The sulfur dioxide gas in the flue gas comes into gas-liquid contact with the calcium carbonate absorption solution in the fiberglass desulfurization tower. The reaction is as follows: Inside the desulfurization tower: CaCO3+SO3+12H2O CaSO3? 12H2O+CO2 oxidation tower: CaSO3? 12H2O+32O2+32H2O CaSO4+2H2O2。
B.脫硫(化學符號:S)(產物:SO2)塔的特性
B. Characteristics of desulfurization (chemical symbol: S) (product: SO2) tower
1.屬於低溫、低壓且時間常數大的設備;
1. It belongs to equipment with low temperature, low pressure, and large time constant;
2.吸收液的氫離子濃度指數及濃度影響脫硫效率;
2. The hydrogen ion concentration index of the absorption solution and its impact on desulfurization efficiency;
3.是處理腐蝕性很強的流體的設備,因而塔內易發生結垢、堵塞和腐蝕。煙氣脫硫脫硝該裝置的腐蝕控製一直是影響裝置長周期安全運行的重點問題之一。
3. It is a device that deals with highly corrosive fluids, so scaling, blockage, and corrosion are prone to occur inside the tower. The corrosion control of flue gas desulfurization and denitrification equipment has always been one of the key issues affecting the long-term safe operation of the equipment.
C.脫硫塔在設計時應注意事項
C. Precautions in the design of desulfurization tower
1.采用垢難以附著的、液體滯留少的簡單塔結構。
1. Adopt a simple tower structure that is difficult for scale to adhere to and has less liquid retention.
2.通過試驗調試控製吸收反應的pH值範圍和吸收液的汽液比,在提高脫硫率的同時減少石灰石的過剩率。
2. By conducting experiments and adjusting the pH range of the absorption reaction and the vapor-liquid ratio of the absorption solution, the excess rate of limestone can be reduced while improving the desulfurization rate.
3.通過數值模擬對玻璃材質鋼脫硫塔流場分析,選擇(xuanze)佳煙氣流速,進行吸收液的佳分配,使吸收液能均勻分布,防止偏流發生,從而提高脫硫效率,減少結垢(屬於化學遺留物)發生。 由以上介紹可見,公司在選擇脫硫塔時應全麵考慮,不僅要有較高的脫硫效率,石灰石的過剩率也不能太高,否則會結垢嚴重,影響塔的使用壽命。
3. Analyze the flow field of the fiberglass desulfurization tower through numerical simulation, select the optimal flue gas flow rate, and distribute the absorption liquid evenly to prevent bias flow, thereby improving desulfurization efficiency and reducing scaling (which belongs to chemical residues). From the above introduction, it can be seen that the company should consider comprehensively when choosing a desulfurization tower. Not only should it have a high desulfurization efficiency, but the excess rate of limestone should also not be too high, otherwise it will cause serious scaling and affect the service life of the tower.
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